Assuming of course you don't mean a copy of a DC game, and you're talking about the GD-ROM disc, you're looking at having to get a coder's cable or broadband adaptor to extract such files. Assuming you've completed that step, the files will (probably) be in .pvr format, for which there's a(n illegal) photoshop plugin floating around as well as a number of to-bmp converters.
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