I'm no expert, but in my experience:
Audio/Data is only if it contains audio tracks files (WAV, MP3 etc) that are burned onto separate tracks on the disc
Data/data is data only
Multisession I've never known a need for, since it doesn't "finalize" the disc and I've run into problems getting these to boot
And scrambling, usually when compiling the CD image with BootDreams it tells you whether or not the BIN is scrambled and will scramble an unscrambled BIN. I've always needed my BINs scrambled to get to work..
I, too, wish I knew of somewhere a little more reliable info was on BD
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