Well the statement 'Music.playFile("Song 1.mp3", true)' means play that file and the true part means for it to loop, so to start with you want that false.
Also you want them to be split up, so to say if song 1 is not playing, play song 2.
But the main thing wrong with what you are doing is having the songs in .mp3 format bacause Lua player doesn't play .mp3 files.
Go here to find out more info on music and sounds in Lua-
http://evilmana.com/tutorials/lua_tutorial_10.php
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