Right, make sure you have a dark_alex custom firmware installed, unsure what has the best compatibility for the games you want but the two are 3.03 OE-B and 3.03 OE-A.
Rip a legally owned PS1 game, (unsure if this is allowed to be talked about on DCemu, if it is not, my apologises). NTSC is better than PAL, but there are converters that can change that.
Once it is ripped, get a GUI for POPstation, make sure it is compatable with the CF you are running. If using 3.03 OE-B, you can save space by compressing the iso.
convert the iso to eboot by using on of the GUI POPstations, place it in the Game folder in your memory stck, and play like you would any other homebrew
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