when you say roms do you mean you trying to burn e.g. a snes emulator with roms or commercial dreamcast games (which is against forum rules, No Warez)
btw when it comes to homebrew there is a huge free and legal amount of game... try dcevo.com for ready to burn cdi images (which can be converted to nero images with a program called cdi2nero), and i find the speed i burn it at does not matter... i think thats a myth
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