Yes, although it won't happen ALL the time.
You must meet these requirements with any given recruit.
- You need an "S" rank for your handling weapon of choice.
- A higher SNS number than 35
- "Gambler" Career helps, too.
You'll be bustin out headshots more than 60% of the time.
The Exclusive Zero character is pretty good with headshots. If I remember correctly his password is 1+2-3, although the clean decent way to unlock him is to have a Metal Gear Graphic Novel save on your Memory stick.
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