I'll see what I can deal with from these.
1. There are some programs that allow you to view avi videos, not sure about .rm, however I find there's less hassle in converting then to a decent bitrate .mp4 and playing it through the XMB (Cross Menu Bar, in case you haven't stumbled across the terminology before, basically the main menu :P)
2. There is a fairly good program that is compatible with MSN's protocol as well as that of AIM, ICQ, GTalk and Yahoo called AFKIM. PSPoste is an E-Mail client but I can't give any details about it as I've never used it myself.
3. As of yet, there are no alternate browsers so you're high and dry on that front.
4. DGen is a pretty good Genesis emulator, it's fast and, well, at least every ROM I've thrown at it has worked. (That's not saying much, I only have about 10.)
5. Snes9xTYL is the best SNES emulator available, it's a tad slow but has pretty good compatibility. There hasn't been a new release in a while, but I believe I recall hearing that there will be a final release at some point in the future.
6. gpSP is the best GBA emulator for the PSP, it can run many games fullspeed. Just don't expect to play games by Camelot, as apparently they had lazy coders and making them compatible is a bitch. Not perfect, but still pretty damn good.
7. Bingo.
8. POPStation no longer requires that you build every EBOOT from the official Hot Shots Golf one from the Playstation Store, many GUIs (The one I use being IceTea) do not require a BASE.PBP of KEYS.BIN file to make a working Playstation game. With said GUI, it's nice and easy to make an ISO/BIN/IMG file into an EBOOT. It also detects game IDs for the ISO you use.
Apparently, you must keep the game ID identical if you wish to use multi-disc games and IceTea assigns a different ID to each disc, that's the only thing you need to look out for in particular. Once you have produced an EBOOT, it simply needs shoved into your PSP\GAME\NAME\ folder (Where NAME is whatever tickles your fancy per game/disc) and it'll run. The only prerequisite to being able to run POPS games is that you're on a suitable Custom Firmware (The most recent being 3.40 OE).
Well, hope that helped, otherwise I've just wasted a bunch of time. If ya need to know anything else, just ask in here or gimme a PM
EDIT: All homebrew ran from 1.5 or Custom Firmwares is accessible via the XMB and I believe all of the emulators that you listed have ROM navigation menus that let you locate a ROM regardless of how you have them arranged.
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